The kinetics of ionic transfer across adsorbed phospholipid layers

V. J. Cunnane; D. J. Schiffrin; M. Fleischmann; G. Geblewicz; D. Williams

doi:10.1016/0022-0728(88)80048-2

The kinetics of ionic transfer across adsorbed phospholipid layers

V. J. Cunnane, D. J. Schiffrin, M. Fleischmann, G. Geblewicz, D. Williams

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Abstract

The inhibition to ion transfer by a monolayer of phospholipid at an immiscible electrolyte interface has been studied using the tetraethylammonium ion as a probe. The decrease of the rate constant for ion transfer has been analysed considering the work of pore formation and the calculated pore size is in agreement with the known dimensions of the probe ion. The proposed model has been used to study the kinetics of assisted transfer of K⁺ with valinomycin as the ionophore.

Original language	English
Pages (from-to)	455-464
Number of pages	10
Journal	Journal of Electroanalytical Chemistry
Volume	243
Issue number	2
DOIs	https://doi.org/10.1016/0022-0728(88)80048-2
Publication status	Published - 25 Mar 1988

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10.1016/0022-0728(88)80048-2

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author = "Cunnane, {V. J.} and Schiffrin, {D. J.} and M. Fleischmann and G. Geblewicz and D. Williams",

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AU - Cunnane, V. J.

AU - Schiffrin, D. J.

AU - Fleischmann, M.

AU - Geblewicz, G.

AU - Williams, D.

PY - 1988/3/25

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N2 - The inhibition to ion transfer by a monolayer of phospholipid at an immiscible electrolyte interface has been studied using the tetraethylammonium ion as a probe. The decrease of the rate constant for ion transfer has been analysed considering the work of pore formation and the calculated pore size is in agreement with the known dimensions of the probe ion. The proposed model has been used to study the kinetics of assisted transfer of K+ with valinomycin as the ionophore.

AB - The inhibition to ion transfer by a monolayer of phospholipid at an immiscible electrolyte interface has been studied using the tetraethylammonium ion as a probe. The decrease of the rate constant for ion transfer has been analysed considering the work of pore formation and the calculated pore size is in agreement with the known dimensions of the probe ion. The proposed model has been used to study the kinetics of assisted transfer of K+ with valinomycin as the ionophore.

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The kinetics of ionic transfer across adsorbed phospholipid layers

Abstract

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