TY - JOUR
T1 - Combining S-DADPS monomer and halloysite nanotube for fabrication superior nanofiltration membrane
AU - Ormancı-Acar, Türkan
AU - Korkut, Sevde
AU - Keskin, Basak
AU - Ağtaş, Meltem
AU - Taş, C. Erdinç
AU - Mutlu-Salmanlı, Öykü
AU - Türken, Türker
AU - Menceloğlu, Yusuf Z.
AU - Ünal, Serkan
AU - Koyuncu, İsmail
N1 - Publisher Copyright:
© 2022 Elsevier Ltd
PY - 2022/8/22
Y1 - 2022/8/22
N2 - In this paper, halloysite nanotubes (HNTs) and disodium-3-3′-disulfone-4-4′-dichlorodiphenylsulfone (S-DADPS) incorporated membranes designed to create a superior nanofiltration membrane. Interfacial polymerization technique was used for the fabrication process and key characterization tests such as contact angle, zeta potential, Scanning Electron Microscope (SEM), and Fourier Transform Infrared Spectroscopy Spectrum (FT-IR) were conducted prior to salt and dye performances tests. Two different dyes, setazol red and reactive orange of 100 ppm, and two different salt solutions, MgSO4 and NaCl of 1000 ppm were used to determine the performances. Consequently, MS-0.01 membrane was selected as best performed membrane, the addition of hydrophilic 0.01% of HNTs and 80% of S-DADPS monomer formed the best recipe to produce a thin film nanocomposite NF membrane. Lastly, pH and temperature resistance tests were performed to further investigate the performance losses of the selected membrane.
AB - In this paper, halloysite nanotubes (HNTs) and disodium-3-3′-disulfone-4-4′-dichlorodiphenylsulfone (S-DADPS) incorporated membranes designed to create a superior nanofiltration membrane. Interfacial polymerization technique was used for the fabrication process and key characterization tests such as contact angle, zeta potential, Scanning Electron Microscope (SEM), and Fourier Transform Infrared Spectroscopy Spectrum (FT-IR) were conducted prior to salt and dye performances tests. Two different dyes, setazol red and reactive orange of 100 ppm, and two different salt solutions, MgSO4 and NaCl of 1000 ppm were used to determine the performances. Consequently, MS-0.01 membrane was selected as best performed membrane, the addition of hydrophilic 0.01% of HNTs and 80% of S-DADPS monomer formed the best recipe to produce a thin film nanocomposite NF membrane. Lastly, pH and temperature resistance tests were performed to further investigate the performance losses of the selected membrane.
KW - Disulfonated diamine monomer
KW - Dye removal
KW - Halloysite nanotubes
KW - Interfacial polymerization
KW - Nanofiltration
UR - http://www.scopus.com/inward/record.url?scp=85135412262&partnerID=8YFLogxK
U2 - 10.1016/j.polymer.2022.125174
DO - 10.1016/j.polymer.2022.125174
M3 - Article
AN - SCOPUS:85135412262
SN - 0032-3861
VL - 255
JO - Polymer
JF - Polymer
M1 - 125174
ER -